O I L     

SYNTHETIC vs REGULAR, ADDITIVES, GRADES

INTRODUCTION

SYNTHETIC OIL

MULTI-VISCOSITY: WHICH GRADE TO USE

Drain Plug Gaskets


Introduction

www.geocities.com/Yosemite/Gorge/6770/motor_oils.htm
Multi viscosity oils are one of the great advances in oils, but they should be chosen wisely. Use a multi grade with the narrowest range of viscosity for the temperatures you are dealing with. In the winter, go by the lowest temperature you will encounter, and in summer, the highest temperature you expect. The polymers can shear and burn, forming deposits that cause ring sticking and other problems. 10W-40, and 5W-30 require a lot of polymers (but not true synthetic oils) to achieve that range. Some "blend" synthetics (not true synthetic-based, but rather hydro processed oils) use a lot of polymers.

Look carefully on 5W-50, 5W-40 by Castrol and Shell "Synthetics" which are actually hydro processed oils and both use mineral oil-based stock from Shell. In most cases high polymer content you can see right away by the percentage of ash. That's what will be left in you engine (cylinders, valves oil channels) after oil circulates there; also, some burns in combustion chamber. It sure forms more sludge and deposits in the engine. This has caused problems in diesel engines, but fewer polymers are better for all engines. The wide viscosity range oils, in general, are more prone to viscosity and thermal breakdown due to the high polymer content. It is the oil that lubricates, not the additives. Oils that can do their job with the fewest additives are the best.

Very few manufactures recommend 10W-40 anymore, and some threaten to void warranties if it is used. And even though 20W-50 has the same 30 point spread, it requires fewer polymers because it starts with a heavier base. AMSOIL (a synthetic) can formulate their 10W-30 and 15W-40 with no viscosity index improvers but uses some in the 10W-40 and 5W-30. Mobil 1 uses no viscosity improvers in their 5W-30, and, presumably, for the new 10W-30.

Viscosity Index is an empirical number indicating the rate of change in viscosity of an oil within a given temperature range. Higher numbers indicate a low change, lower numbers indicate a relatively large change. The higher the number the better. This is one major property of an oil that keeps your bearings happy. These numbers can only be compared within a viscosity range. It is not an indication of how well the oil resists thermal breakdown.

Flash point is the temperature at which an oil gives off vapors that can be ignited with a flame held over the oil. The lower the flash point the greater tendency for the oil to suffer vaporization loss at high temperatures and to burn off on hot cylinder walls and pistons. The flash point can be an indicator of the quality of the base stock used. The higher the flash point the better. 400 F is the minimum to prevent possible high consumption. Flash point is in degrees F.

Pour point is 5 degrees F above the point at which a chilled oil shows no movement at the surface for 5 seconds when inclined. This measurement is especially important for oils used in the winter. A borderline pumping temperature is given by some manufacturers. This is the temperature at which the oil will pump and maintain adequate oil pressure. This was not given by a lot of the manufacturers, but seems to be about 20 degrees F above the pour point. The lower the pour point the better. Pour point is in degrees F.

Percent sulfated ash is how much solid material is left when the oil burns. A high ash content will tend to form more sludge and deposits in the engine. Low ash content also seems to promote long valve life. Look for oils with a low ash content.

Percent zinc is the amount of zinc used as an extreme pressure, anti- wear additive. The zinc is only used when there is actual metal to metal contact in the engine. Hopefully the oil will do its job and this will rarely occur, but if it does, the zinc compounds react with the metal to prevent scuffing and wear. A level of .11% is enough to protect an automobile engine for the extended oil drain interval, under normal use. Those of you with high revving, air cooled motorcycles or turbo charged cars or bikes might want to look at the oils with the higher zinc content. More doesn't give you better protection, it gives you longer protection if the rate of metal to metal contact is abnormally high. High zinc content can lead to deposit formation and plug fouling.

Brand VI Flash Pour %ash %zinc 20W-50 AMSOIL (old) 136 482 -38 <.5 --- AMSOIL (new) 157 507 -44 --- --- Castrol GTX 122 440 -15 .85 .12 Exxon High Performance 119 419 -13 .70 .11 Havoline Formula 3 125 465 -30 1.0 --- Kendall GT-1 129 390 -25 1.0 .16 Pennzoil GT Perf. 120 460 -10 .9 --- Quaker State Dlx. 155 430 -25 .9 --- Red Line 150 503 -49 --- --- Shell Truck Guard 130 450 -15 1.0 .15 Spectro Golden 4 174 440 -35 --- .15 Spectro Golden M.G. 174 440 -35 --- .13 Unocal 121 432 -11 .74 .12 Valvoline All Climate 125 430 -10 1.0 .11 Valvoline Turbo 140 440 -10 .99 .13 Valvoline Race 140 425 -10 1.2 .20 Valvoline Synthetic 146 465 -40 <1.5 .12 20W-40 AMSOIL 124 50 -49 --- --- Castrol Multi-Grade 110 440 -15 .85 .12 Quaker State 121 415 -15 .9 --- 15W-50 Chevron 204 415 -18 .96 .11 Mobil 1 170 470 -55 --- --- Mystic JT8 144 420 -20 1.7 .15 Red Line 152 503 -49 --- --- 5W-50 Castrol Syntec 180 437 -45 1.2 .10 Quaker State Synquest 173 457 -76 --- --- Pennzoil Performax 176 --- -69 --- --- 5W-40 Havoline 170 450 -40 1.4 --- 15W-40 AMSOIL (old) 135 460 -38 <.5 --- AMSOIL (new) 164 462 -49 --- --- Castrol 134 415 -15 1.3 .14 Chevron Delo 400 136 421 -27 1.0 --- Exxon XD3 --- 417 -11 .9 .14 Exxon XD3 Extra 135 399 -11 .95 .13 Kendall GT-1 135 410 -25 1.0 .16 Mystic JT8 142 440 -20 1.7 .15 Red Line 149 495 -40 --- --- Shell Rotella w/XLA 146 410 -25 1.0 .13 Valvoline All Fleet 140 --- -10 1.0 .15 Valvoline Turbo 140 420 -10 .99 .13 10W-30 AMSOIL (old) 142 480 -70 <.5 --- AMSOIL (new) 162 520 -76 --- --- Castrol GTX 140 415 -33 .85 .12 Chevron Supreme 150 401 -26 .96 .11 Exxon Superflo Hi Perf 135 392 -22 .70 .11 Exxon Superflo Supreme 133 400 -31 .85 .13 Havoline Formula 3 139 430 -30 1.0 --- Kendall GT-1 139 390 -25 1.0 .16 Mobil 1 160 450 -65 --- --- Pennzoil PLZ Turbo 140 410 -27 1.0 --- Quaker State 156 410 -30 .9 --- Red Line 139 475 -40 --- --- Shell Fire and Ice 155 410 -35 .9 .12 Shell Super 2000 155 410 -35 1.0 .13 Shell Truck Guard 155 405 -35 1.0 .15 Spectro Golden M.G. 175 405 -40 --- --- Unocal Super 153 428 -33 .92 .12 Valvoline All Climate 130 410 -26 1.0 .11 Valvoline Turbo 135 410 -26 .99 .13 Valvoline Race 130 410 -26 1.2 .20 Valvoline Synthetic 140 450 -40 <1.5 .12 5W-30 AMSOIL (old) 168 480 -76 <.5 --- AMSOIL (new) 186 464 -76 --- --- Castrol GTX 156 400 -35 .80 .12 Chevron Supreme 202? 354 -46 .96 .11 Chevron Supreme Synt. 165 446 -72 1.1 .12 Exxon Superflow HP 148 392 -22 .70 .11 Havoline Formula 3 158 420 -40 1.0 --- Mobil 1 165 445 -65 --- --- Mystic JT8 161 390 -25 .95 .1 Quaker State 165 405 -35 .9 --- Red Line 151 455 -49 --- --- Shell Fire and Ice 167 405 -35 .9 .12 Unocal 151 414 -33 .81 .12 Valvoline All Climate 135 405 -40 1.0 .11 Valvoline Turbo 158 405 -40 .99 .13 Valvoline Synthetic 160 435 -40 <1.5 .12 Chart courtesy of : www.geocities.com/Yosemite/Gorge/6770/motor_oils.htm



SYNTHETIC OIL

Synthesized in chemical plants by reacting components to make a product with the desired properties, synthetic fluids can be virtually anything the chemist needs them to be. Poly-Alpha-Olefins (PAO) are the most widely used synthetic industrial lubricants available today. They are similar to prohibitively expensive super pure parafinic mineral oil but contain no sulfur, no phosphorus, and no metals. And PAOs consist of identical molecules of pure hydrocarbons that can withstand high temperatures without decomposing. Having eliminated mineral oil's greatest weakness—unwanted molecular "hitchhikers"—the consistent molecular structure of synthetic oil is clearly superior.

So why isn't synthetic oil in every engine, transmission, and differential? Because it costs more to produce. The key ingredients are decene molecules. Decene is a linear molecule with 10 carbons, and it's synthesized by first linking together five molecules of ethylene, each of which contains two carbons. The second synthesis step involves polymerization of the decene. Two or more decene molecules are combined to form short chain-length polymers, and from these, PAOs result. No doubt, it's a capital-intensive manufacturing process that unavoidably leads to higher retail prices than cheaper-to-produce mineral oil.

From: http://www.hotrod.com/techarticles/79838/

---------------

Since the original (pure) synthetic basestock (polyalphaolefin or PAO) costs approximately 3 times as much as the Group III basestock, most of the oil blenders switched to the Group III basestock, which significantly increased their profit margins (the price of synthetic oils didn't drop, strangely enough, to accommodate this cheaper basestock, which makes up more than 70% of a bottle of oil).

In Europe, blenders still need to use some PAO in order to meet the toughest ACEA specs. In the US, Mobil 1, Amsoil, Red Line and Royal Purple are the only ones you can be (reasonably) SURE OF still using PAO. If you can get a material safety data sheet (MSDS) for the oil you are interested in, look for PAO or polymer or oligomer of 1-decene as a component for a tip-off. Synthetic blends contain some amount (not defined, as far as I know) of synthetic basestock. The small amount of viscosity modifier present in most multi-grade oils probably fulfils this requirement, making synthetic blends another profit centre for the oil blenders.

- From: http://faq.f650.com/FAQs/OILFAQ.htm

---------------



MULTI-VISCOSITY INTERPRETED

http://www.scionlife.com/forums/archive/o_t__t_117948__what-oil-does-eveyone-with-forced-inductions-use.html

5W-30 Lowest Operating Temperature: -13 F Provides excellent fuel economy and low temperature performance in most late model automobiles. Especially recommended for new cars.

10W-30 Lowest Operating Temperature: 0° F Most frequently recommended viscosity grade for most automobile engines, including high performance multi-valve engines and turbo-charged engines.

10W-40 Lowest Operating Temperature: 0° F The first multi-grade introduced. A good choice for controlling engine wear and preventing oil breakdown from oxidation due to hotter-than-normal running conditions. Note: Always check your owner's manual or warranty requirements before using this grade.

20W-50 Lowest Operating Temperature: 15° F Provides maximum protection for high performance, high RPM racing engines. Excellent choice for high temperature and heavy loads such as driving in the desert or towing a trailer at high speeds for long periods of time.

SAE 30 Lowest Operating Temperature: 15° F For cars and light trucks, where recommended by manufacturers.

SAE 40 Lowest Operating Temperature: 32° F Not recommended when cold temperature starting is required.

• Thinner oil (e.g., 10W30) lubricates narrow passages better in cold conditions; less prone to "sludge"; better for newer, "tighter" engines;

• thicker oil (e.g., 10W40, 20W50) reduces oil consumption (burning) in older, worn engines; better protection in hot conditions;



How do oil viscosity ratings relate to reality?


In a multi-viscosity oil such as the 20-50 in your example, the oil acts like a 20 weight (ie, thinner) when the car is cold, and like a 50 weight (thicker) when it is warm. This does _not_ mean that the oil actually gets thicker as the car gets hotter. The 20-50 oil would simply not thin as much as a straight 20 weight oil. And of course the converse is also true -- when cold, the 20-50 oil would not get as thick as a straight 50 weight.

What does "multi-viscosity" mean? (I would think it would be next-to-impossible to create anything else).

"Multi-viscosity" doesn't refer to any changes in the oil's thickness caused by changes in temperature. It is a simply a rating of the _relative_ viscosity of an oil compared to other oils -- which could be thinner or thicker.

From http://home.att.net/~ferrari/oil1.htm



OIL: ENGINE FLUSH, ADDITIVES, OIL PRESSURE GAUGE [JITTERY, & POSSIBLE CAUSES)...

{Oil Pressure Gauge Jittery]
[http://www.ford-trucks.com/dcforum/DCForumID77/884.html]
If pressure still flutters you have either an oil leak (internal - like a bad journal), an oil passage blockage (try changing the oil AND FILTER), a stuck pressure releif valve (relpace this for a few bucks), or a problem with the pump (ouch).
-----
[Idea: Maybe some debris got loose & clogged the filter, thus interfering with the flow... othe rmessages mention High Filtration oil filters possibly causing this,,, maybe excess debris is crating the same effect - RJ]

[http://autos.groups.yahoo.com/group/fordexplorer/message/359]
I was thinking that without this possibly it is what is affecting the gauges. The gauge has a resistor on the back( for lack of a better word ) which keeps the gauge in a sort of comfort zone for the driver. Put an aftermarket gauge on the and bypass it around the factory on and you will be amazed at how fast the oil pressure rises and falls compared to what the factory on is doing. What I was thinking (but without proof) is if the oil filter does not have the valve or it is malfunctioning the resistor (again lack of a better word) might read it as a failure giving you a low oil pressure readout. Mainly because it has fallen outside its set operating values. I have no proof this is what happening and it is just a theory based on what I had read.



Engine Flushing


[http://www.ceramalube.com/]

While oil filters remove particulate over 25 microns, sludge, tar, varnish, and wear metals less than 25 microns continue to circulate within the engine and accumulate within the passageways, oil pump and oil pan. These contaminants cause engine wear, reduce lubrications, block oil channels and cause sticky lifters and valves.


----
Ceramalube Engine Flush is added to the oil prior to an oil change. The engine is run for about 15 minutes and when the used oil is drained, sludge and sediments are removed.

Properties:
- Cleans oil pump, sensor, channels etc. /
- Helps free sticky lifters and valves. /
- Cleans engine within 15 minutes. /
- Safe for gaskets, rings and other rubber parts

Additional information:
Oil contaminants are known to:
- raise viscosity /
- increase corrosion /
- interfere with oil additives /
- and can cause severe engine damage

Can content
250 ml, sufficient for sumps [?] of 0.75 - 1,50 Gallon engine oil
-------


Oil Drain Plug Gaskets


http://72.14.207.104/search?q=cache:DPgL_AY6U68J:www.tdr1.com/forums/showthread.php%3Ft%3D118712+dodge+%22oil+drain+plug+gaskets%22++price+-pdf+&hl=en

I keep a few Mopar replacement oil drain plug gaskets around. The part number is 04882049. This little gasket is what causes so many people trouble with their drain plugs. They neglect to replace this gasket, and as a result end up over tightening the drain plug to get it to seal. A good rule of thumb would be to replace the gasket every oil change, but I don't see that happening with most owners. Almost every new car now comes with a alloy sealing washer/gasket, that is suppose to be replaced with every oil change. These small sealing washers are very cheap, around .10, and come taped to the side of oil filters when bought thru reputable OEM parts suppliers...[In what universe?]



TO MESSAGEBOARD > > >

HOME